Sodium sulfide supplier Distributor Manufacture in Kolkata India
EAST INDIA CHEMICAL Sodium sulfide is the chemical compound with the formula Na2S, or more commonly its hydrate Na2S·9H2O. Both are colorless water-soluble salts that give strongly alkaline solutions. When exposed to moist air, Na2S and its hydrates emit hydrogen sulfide, which smells like rotten eggs. Some commercial samples are specified as Na2S·xH2O, where a weight percentage of Na2S is specified. Commonly available grades have around 60% Na2S by weight, which means that x is around 3. Such technical grades of sodium sulfide have a yellow appearance owing to the presence of polysulfides. These grades of sodium sulfide are marketed as 'sodium sulfide flakes'. Although the solid is yellow, solutions of it are colorless.
Uses
Sodium sulfide is primarily used in the kraft process in the pulp and paper industry.
It is used in water treatment as an oxygen scavenger agent and also as a metals precipitant; in chemical photography for toning black and white photographs; in the textile industry as a bleaching agent, for desulfurizing and as a dechlorinating agent; and in the leather trade for the sulfidation of tanning extracts. It is used in chemical manufacturing as a sulfonation and sulfomethylation agent. It is used in the production of rubber chemicals, sulfur dyes, and other chemical compounds. It is used in other applications including ore flotation, oil recovery, making dyes, and detergent. It is also used during leather processing, as an unhairing agent in the liming operation.
The reagent in organic chemistry
Alkylation of sodium sulfide give thioethers:
Na2S + 2 RX → R2S + 2 NaX
Even aryl halides participate in this reaction. Sodium sulfide can be used as a nucleophile in Sandmeyer type reactions. Sodium sulfide reduces1,3-dinitrobenzene derivatives to the 3-nitroanilines. An aqueous solution of sodium sulfide can be refluxed with nitro carrying azo dyes dissolved in dioxane and ethanol to selectively reduce the nitro groups to amine; while other reducible groups, e.g. azo group, remain intact. Sulfide has also been employed in photocatalytic applications.