Sodium Chlorate, Manufacturers, Suppliers and Exporters in kolkata india
Sodium chlorate is an inorganic compound with the chemical formula NaClO3. It is a white crystalline powder that is readily soluble in water. It is hygroscopic. It decomposes above 300 °C to release oxygen and leave sodium chloride. Several hundred million tons are produced annually, mainly for applications in bleaching paper.
Uses
The main commercial use for sodium chlorate is for making chlorine dioxide (ClO2). The largest application of ClO2, which accounts for about 95% of the use of chlorate, is in bleaching of pulp. All perchlorate compounds are produced industrially by the oxidation of solutions of sodium chlorate by electrolysis.
Herbicides
Sodium chlorate is used as a non-selective herbicide. It is considered phytotoxic to all green plant parts. It can also kill through root absorption.
Sodium chlorate may be used to control a variety of plants including morning glory, canada thistle, johnson grass, bamboo, Ragwort, and St John's wort. The herbicide is mainly used on non-crop land for spot treatment and for total vegetation control on areas including roadsides, fenceways, and ditches. Sodium chlorate is also used as a defoliant and desiccant for:
Cotton
Safflower
Corn
Flax
Peppers
Soybeans
Grain sorghum
Southern peas
Dry beans
Rice
Sunflowers
If used in combination with atrazine, it increases the persistence of the effect. If used in combination with 2,4-D, performance is improved. Sodium chlorate has a soil sterilant effect. Mixing with other herbicides in aqueous solution is possible to some extent, so long as they are not susceptible to oxidation.
The sale of sodium chlorate as a weedkiller was banned in the European Union in 2009, with existing stocks to be used within the following year.
Chemical oxygen generation
Chemical oxygen generators, such as those in commercial aircraft, provide emergency oxygen to passengers to protect them from drops in cabin pressure. Oxygen is generated by high-temperature decomposition of sodium chlorate:
2 NaClO3 → 2 NaCl + 3 O2
Heat required for this reaction is generated by oxidation of a small amount of iron powder mixed with the sodium chlorate, and the reaction consumes less oxygen than is produced. Barium peroxide (BaO2) is used to absorb the chlorine that is a minor product in the decomposition. An ignitor charge is activated by pulling on the emergency mask. Similarly, the Solidox welding system used pellets of sodium chlorate mixed with combustible fibers to generate oxygen.